Methyl ethyl ketone peroxide (Molecule of the Month for March 2007)
MEKP, Ethyl methyl ketone peroxide
Methyl ethyl ketone peroxide (MEKP) is an organic peroxide, a high explosive similar to acetone peroxide, and is very dangerous to prepare. MEKP is a colorless, oily liquid at room temperature and pressure, while acetone peroxide is a white solid. It is slightly less sensitive to shock and temperature than acetone peroxide, and more stable in storage. It is prepared from butanone and hydrogen peroxide.
Dilute solutions of MEKP are used in industry and by hobbyists as the catalyst which initiates the polymerization of polyester resins used in glass-reinforced plastic, and casting. MEKP does this through the production of free radicals.
It has been reported that MEKP might be the explosive that was to be used in the alleged 2006 transatlantic aircraft plot to destroy planes flying from the United Kingdom to the United States. Acetone peroxide, TATP, is another reported possibility.
Formal Chemical Name (IUPAC)
2-hydroperoxy-2-((2-hydroperoxybutan-2-yl)peroxy)butane
References
http://en.wikipedia.org/wiki/Methyl_ethyl_ketone_peroxide
http://en.wikibooks.org/wiki/Chemical_synthesis/Methyl_ethyl_ketone_peroxide
Update by Karl Harrison
(Molecule of the Month for
March 2007
)
All the images on this web site are are made available with a Creative Commons Attribution license and so can be used as long as the attribution © Karl Harrison 3DChem.com is written with the image. High resolution images and illustrations are available on request.